Bookcover of Low Temperature Oxidation of Hydrocarbons
Booktitle:

Low Temperature Oxidation of Hydrocarbons

Detailed Chemical Kinetics Modeling

VDM Verlag Dr. Müller (2008-09-30 )

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ISBN-13:

978-3-639-08765-9

ISBN-10:
3639087658
EAN:
9783639087659
Book language:
English
Blurb/Shorttext:
Low-temperature oxidation (below 1000K) of hydrocarbon fuels is a complex process. It exhibits negative temperature coefficient behavior where overall reactivity decreases with increasing temperature. It is necessary to understand the oxidation mechanism of fuels because of its importance in various applications such as HCCI engines. The conventional oxidation mechanism of alkanes has been greatly affected by the identification of a new concerted elimination pathway that produces alkene and hydroperoxy radical from alkylperoxy. This pathway reduces the chain branching via the conventional route of alkylperoxy isomerization. This leaves us with the quest for the new chain-branching pathways. This study focuses on the ethane oxidation because it is absolutely necessary to understand it for modeling of higher hydrocarbons and “real” fuels. Complex analysis methods were used to treat the chemically activated and thermally activated reactions that yield temperature as well as pressure- dependent reaction rate constants.
Publishing house:
VDM Verlag Dr. Müller
Website:
http://www.vdm-verlag.de
By (author) :
Naik Chitralkumar
Number of pages:
168
Published at:
2008-09-30
Stock:
Available
Category:
Technology
Price:
68.00 €
Keywords:
reaction kinetics, NTC, auto ignition, detailed mechanism, chemically activated reactions, chemically activated reactions

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