Virial theorem and the two molecule interaction potential
The formula for the physical interaction potential of two molecules depending on the distance between them
978-620-0-09556-5
6200095566
56
2019-05-15
23.90 €
eng
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A method for determining the parameters of the two-molecule interaction potential is shown by the example of the Mie potential or the four-parameter Lennard-Jones potential (GLJ). The application of the virial theorem with respect to the Mie potential allows one to determine exponents at the intermolecular distance. The application of the theory of pair collisions for determination of the intermolecular repulsion potential is shown by the example of a namber of substances. The statistic characteristic of gases that allows one to formulate the intermolecular potential is found. The time-averaged relative arrangement of molecules in a gas corresponds to a fase-centered cubic lattice.
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